LIU Xiaolan,FANG Hui,WANG Daoping,et al.Study on Vertical Distribution Characteristics and Occurrence Forms of Heavy Metals in Soil of Water and Drought Rotation in Carbonate Area[J].Northern Horticulture,2022,(11):67-74.[doi:10.11937/bfyy.20215286]
碳酸盐岩地区水旱轮作土壤重金属垂直分布特征及赋存形态研究
- Title:
- Study on Vertical Distribution Characteristics and Occurrence Forms of Heavy Metals in Soil of Water and Drought Rotation in Carbonate Area
- Keywords:
- rotation of water and drought; soil heavy metals; vertical distribution; occurrence form; ecological hazard
- 文献标志码:
- A
- 摘要:
- 以贵州遵义播州区石板镇水旱轮作的石灰性水稻土为试材,利用电感耦合等离子发射光谱,测定了土壤中重金属Cd、Cr、Cu、Zn和Pb的含量,研究了碳酸盐岩地区水旱轮作土壤重金属赋存形态、垂直分布、淋滤迁移特征以及生态危害,以期为碳酸盐岩地区农田土壤重金属污染综合防治、农产品质量安全和地下水安全提供参考依据。结果表明:在国家土壤环境质量标准(GB15618-2018)规定范围内,土壤重金属Cd超标率达80%,重金属Cr、Cu、Zn和Pb样点达标率为100%;研究区土壤除了Cr之外,土壤pH、有机质、重金属Cd、Zn、Cu和Pb含量均随着土层深度的加深呈下降趋势;各土层重金属淋失率呈现Zn>Cu>Cd>Cr>Pb的特征;5种重金属各形态含量随着土层深度的加深无明显变化,且5种重金属在各土层中主要以残渣态存在;地累积综合污染指数法中,研究区各土层均无污染,而综合潜在生态风险指数法中,研究区各土层均为轻微风险等级,其中Cd是最主要的生态风险元素,其次是Pb。
- Abstract:
- Taking the calcareous paddy soil in Shiban Town,Bozhou District,Zunyi,Guizhou Province as the test material,the contents of heavy metals Cd,Cr,Cu,Zn and Pb in the soil were determined by inductively coupled plasma emission spectrometry.The occurrence forms,vertical distribution,leaching and migration characteristics and ecological hazards of heavy metals in the soil of water and drought rotation in carbonate rock area were studied,in order to provide reference for the comprehensive prevention and control of heavy metal pollution in farmland soil in carbonate rock area and scientific basis for the quality and safety of agricultural products and groundwater safety.The results showed that within the scope of national soil environmental quality standard (GB15618-2018),the exceeding standard rate of soil heavy metal Cd was 80%,and the reaching standard rate of heavy metal Cr,Cu,Zn and Pb was 100%.In addition to Cr,the contents of soil pH,organic matter,heavy metals Cd,Zn,Cu and Pb decreased with the deepening of soil depth.The leaching rate of heavy metals in each soil layer showed the characteristics of Zn>Cu>Cd>Cr>Pb.The content of each form of the five heavy metals did not change significantly with the deepening of soil depth,and the five heavy metals mainly existed in residual form in each soil layer.In the cumulative comprehensive pollution index method,all soil layers in the study area were free of pollution,while in the comprehensive potential ecological risk index method,all soil layers in the study area were at a slight risk level,in which Cd was the most important ecological risk element,followed by Pb.
参考文献/References:
[1]武永锋,刘丛强,涂成龙.贵阳城市土壤重金属元素形态分析[J].矿物学报,2008,28(2):177-180.[2]方慧,柳小兰,颜秋晓,等.贵州油菜各器官在不同生育时期对土壤重金属的富集[J].北方园艺,2018(5):111-117.[3]杨永忠.贵州环境异常元素地球化学研究[J].贵州地质,1999,16(1):66-72.[4]随晋.重金属的一般存在形态和转化方式[J].广东化工,2021,48(11):64-65.[5]杨少斌,孙向阳,张骏达,等.北京市五环内绿地土壤4种重金属的形态特征及其生物有效性[J].水土保持通报,2018,38(3):79-85,93.[6]楚纯洁,马建华.郑州市典型城市土壤剖面Zn、Ni分布特征分析[J].四川师范大学学报(自然科学版),2012,35(3):418-424.[7]谈恒文,张子军,安丰芹.日照市东港区地下水环境质量现状评价[J].地球学报,2005,26(2):173-177.[8]国家环境保护局,中国环境监测总站.中国土壤元素背景值[M].北京:中国环境科学出版社,1990.[9]WEISSKOPF A,FULLER D Q.Buckwheat:Origins and development[J].World Development,2014,33(2):242-257.[10]HAKANSON L.An ecological risk index for aquatic pollution control:Asediment ecological approach[J].Water Research,4980,14(8):975-1001.[11]吴远航,朱红梅,秦俊虎.铅锌矿区稻田土壤中重金属形态分析及生态风险评价[J].环保科技,2021,27(3):31-52.[12]陈凤,董泽琴,王程程,等.锌冶炼区耕地土壤和农作物重金属污染状况及风险评价[J].环境科学,2017,38(10):4360-4369.[13]TU C L,HE T B,LIU C Q,et al.Effects of land use and parent materials on trace elements accumulation in topsoil[J].Journal of Environmental Quality,2013,42:103-110.[14]郑国璋.关中娄土剖面中重金属元素的垂直分布规律研究[J].地球学报,2008,29(1):109-115.[15]白军红,赵庆庆,卢琼琼,等.白洋淀沼泽化区域土壤重金属含量的剖面分布特征:以烧车淀为例[J].湿地科学,2013,11(2):271-275.[16]LI F,FAN Z,XIAO P,et al.Contamination,chemical speciationand vertical distribution of heavy metals in soils of an old and large industrial zone in Northeast China[J].Environmental Geology,2009,57(8):1815-1823.[17]南忠仁,李吉均.干旱区耕作土壤中重金属镉铅镍剖面分布及行为研究:以白银市区灰钙土为例[J].干旱区研究,2000,17(4):39-45.[18]李向宏,王艳红,郑国璋.临汾盆地农田褐土剖面重金属的分布迁移特征[J].河北师范大学学报,2016,40(2):168-171.[19]高庚申,陈婷婷,迟峰,等.贵州某废弃铝厂土壤重金属污染特征及风险评价[J].有色金属工程,2020,10(7):124-130.[20]杨倩,鲁新川,殷建国,等.甘肃嘉峪关市表层土壤重金属空间分布与评价[J].沉积学报,2019,37(5):1006-1015.[21]王永平,周子柯,滕昊蔚,等.滇南小流域不同土地利用类型土壤重金属形态特征及污染评价[J].环保科技,2021,27(1):38-45.[22]姚文文,陈文德,黄钟宣,等.重庆市主城区土壤重金属形态特征及风险评价[J].西南农业学报,2021,34(1):159-164.[23]付丽丽,姚常琦,李学斌,等.沈阳农用土地重金属污染评价与来源分析[J].广东农业科学,2013(16):178-181.[24]孙境蔚.铁观音茶园土壤:茶树体系中金属的迁移特征及来源解析[D].泉州:华侨大学,2020.[25]亚龙,杨志斌,王乔林,等.雄安新区农田土壤-农作物系统重金属潜在生态风险评估及其源解析[J].环境科学,2021,42(4):2003-2015.[26]唐世琪,刘秀金,杨柯,等.典型碳酸盐岩区耕地土壤剖面重金属形态迁移转化特征及生态风险评价[J].环境科学,2021,42,(8):3913-3923.[27]胡青青,沈强,陈飞,等.重构土壤垂直剖面重金属 Cd 赋存形态及影响因素[J].环境科学,2020,41(6):2878-2888.[28]杨新明,庄涛,韩磊,等.小清河污灌区农田土壤重金属形态分析及风险评价[J].环境化学,2019,38(3):644-652.[29]程芳,程金平,桑恒春,等.大金山岛土壤重金属污染评价及相关性分析[J].环境科学,2013,34(3):1062-1066.
相似文献/References:
[1]陈碧华,郭卫丽,王广印,等.地肤对大棚菜田土壤重金属的修复效应研究[J].北方园艺,2016,40(07):170.[doi:10.11937/bfyy.201607043]
CHEN Bihua,GUO Weili,WANG Guangyin,et al.Research of Remediation Effect of Kochia scoparia on Heavy Metal Contaminated Vegetable Field Soil in Plastic Shed[J].Northern Horticulture,2016,40(11):170.[doi:10.11937/bfyy.201607043]
[2]张路,王利华,桂和荣,等.土壤重金属胁迫与植物相关miRNA的研究进展[J].北方园艺,2017,41(18):180.[doi:10.11937/bfyy.20165188]
ZHANG Lu,WANG Lihua,GUI Herong,et al.Progress on the Soil Heavy Metal Stress and Associated miRNA of Plant[J].Northern Horticulture,2017,41(11):180.[doi:10.11937/bfyy.20165188]
[3]孙全平.拉萨市典型区域农田土壤重金属空间分布及生态风险评价[J].北方园艺,2018,42(22):124.[doi:10.11937/bfyy.20174296]
Spatial Distribution and Risk Assessment of Soil Heavy Metals in Typical Region of Lhasa City.Spatial Distribution and Risk Assessment of Soil Heavy Metals in Typical Region of Lhasa City[J].Northern Horticulture,2018,42(11):124.[doi:10.11937/bfyy.20174296]
[4]周丽,杨丰,金宝成,等.喀斯特山区不同土地利用方式对土壤重金属的影响[J].北方园艺,2019,43(08):110.[doi:10.11937/bfyy.20183380]
ZHOU Li,YANG Feng,JIN Baocheng,et al.Influence of Different Land Use Types on Soil Heavy Metals in the Karst Mountain Area[J].Northern Horticulture,2019,43(11):110.[doi:10.11937/bfyy.20183380]
[5]赵瑞芬,程滨,滑小赞,等.忻州市灌区土壤重金属污染评价及分布特征分析[J].北方园艺,2021,(06):81.[doi:10.11937/bfyy.20201393]
ZHAO Ruifen,CHENG Bin,HUA Xiaozan,et al.Evaluation and Distribution Characteristics of Heavy Metal Pollution in Soil of Xinzhou Irrigation District[J].Northern Horticulture,2021,(11):81.[doi:10.11937/bfyy.20201393]
[6]李奕,陈金萍,李祥余,等.不同农业土地利用方式对土壤重金属含量影响及生态风险评价[J].北方园艺,2021,(18):95.[doi:10.11937/bfyy.20210544]
LI Yi,CHEN Jinping,LI Xiangyu,et al.Effects of Different Agricultural Land Use Patterns on Soil Heavy Metal Content and Ecological Risk Assessment[J].Northern Horticulture,2021,(11):95.[doi:10.11937/bfyy.20210544]
[7]杨晓杰,崔向新,珊丹,等.荒漠草原金矿周边土壤重金属分布特征及生态风险评价[J].北方园艺,2022,(19):78.[doi:10.11937/bfyy.20220193]
YANG Xiaojie,CUI Xiangxin,SHAN Dan,et al.Distribution Characteristics and Ecological Risk Assessment of Heavy Metals in Soils Around Gold Deposits in Desert Steppe[J].Northern Horticulture,2022,(11):78.[doi:10.11937/bfyy.20220193]
备注/Memo
第一作者简介:柳小兰(1988-),女,硕士,副研究员,现主要从事土壤资源保护与利用等研究工作。E-mail:952741179@qq.com.责任作者:张清海(1982-),男,博士,研究员,现主要从事土壤资源保护与利用、环境科学等研究工作。E-mail:zhqh8@163.com.基金项目:国家自然科学基金资助项目(42167054);地区科学基金资助项目(21767006);国家自然科学基金资助项目(31960507);贵州省科技计划资助项目(黔教合KY字[2020]014,黔科合服企[2020]4013)。收稿日期:2021-12-27