LUO Huili,XIE Zhenzeng,YANG Yixuan,et al.Effects of Commonly Used Surfactants and Their Combination on Soil Phosphorus Loss and Retention[J].Northern Horticulture,2022,(24):59-64.[doi:10.11937/bfyy.20221412]
常用表面活性剂及其复配使用对土壤磷流失及再吸持的影响
- Title:
- Effects of Commonly Used Surfactants and Their Combination on Soil Phosphorus Loss and Retention
- Keywords:
- surfactants; phosphorus; soil; loss
- 文献标志码:
- A
- 摘要:
- 以3种常用表面活性剂NP-10（壬基酚聚氧乙烯醚10 mol）、TW-80（聚山梨醇酯-80）和SDS（十二烷基硫酸钠）为试材，并将非离子与阴离子表面活性剂复配进行试验,采用土柱淋溶试验，通过测定淋出液中磷含量，淋溶后土壤磷吸附量、Zeta电位及土壤水分特性等，研究了非离子表面活性剂及其复配淋溶下对表层土壤磷流失和再吸持的影响，以期为减少农业面源污染提供参考依据。结果表明:NP-10促进了磷流失，磷流失总量比CK增加了26.04%；但TW-80对土壤磷流失影响相对较小。NP-10、TW-80分别与SDS复配淋溶降低了土壤磷流失量，但仍高于CK 5.24%和13.67%。按磷流失总量，各试验组排序依次为SDS-5>NP-10-5>TW-80+SDS>TW-80-5>NP-10+SDS>CK。土壤磷流失与土壤Zeta电位、土壤持水性均呈正相关。而淋溶后土壤磷吸附量和Zeta电位的相关性最强（R=0.875 0）；而与磷流失总量相关性弱。表面活性剂改变了土壤表面电性，对磷的再吸附及后续磷供给有较大影响。
- Abstract:
- Three common surfactants that NP-10 (Nonylphenol Ethoxylate 10 mol),TW-80 (polysorbate-80) and SDS (sodium dodecyl sulfate) were selected as experimental materials,and the mixture of non-ionic and anionic surfactants was also taken in test.The soil column leaching test was carried out and phosphorus content in leaching solution,soil phosphorus adsorption capacity,Zeta potential and soil moisture characteristics were analyzed to explore the effects of non-ionic surfactants and the mixture surfactants on soil phosphorus loss and retention under leaching,in order to provide reference for reducing agricultural non-point source pollution.The results showed that NP-10 promoted phosphorus loss,comparing with CK,the increase of total phosphorus loss was 26.04%.Meanwhile,TW-80 had relatively little effect on soil phosphorus loss.In combined leaching of NP-10 and TW-80 with SDS respectively,though soil phosphorus loss decreased,but it was still 5.24% and 13.67% higher than CK.According to total phosphorus loss,the order of experimental groups was SDS-5>NP-10-5>TW-80+SDS>TW-80>NP-10+SDS>CK.Soil phosphorus loss was positively correlated with soil Zeta potential and soil water holding capacity.Correlation between soil phosphorus adsorption after leaching and Zeta potential was the strongest (R=0.875 0) while the correlation with total phosphorus loss was weak.Surfactants changed the surface electrical properties of soil and it had great influence on phosphorus re-adsorption and subsequent phosphorus supply.
参考文献/References:
[1]赵永杰,裴鸿.2020年中国表面活性剂行业原料及产品统计分析[J].日用化学品科学,2021,44(6):1-8.[2]KUMAR N,TYAGI R.Characteristic and application of anionic dimeric surfactants:A review[J].Tenside Surfactants Detergents,2019,56(3):172-179.[3]WANG T F,CHANG D J,HUANG D,et al.Application of surfactants in papermaking industry and future development trend of green surfactants[J].Applied Microbiology and Biotechnology,2021,105(20):7619-7634.[4]LIU Y T,CHEN S，LIN S,et al.The phase behavior and solubilization ability of nonionic surfactant-distillate fraction of crude oil microemulsion system[J].Colloids & Surfaces A:Phys Eng Asp,2020,603:125181.[5]林琴,周利,罗逢健,等.超高效液相色谱-串联质谱联法测定茶园用农药制剂中烷基酚聚氧乙烯醚含量[J].茶叶科学,2019,39(1):105-113.[6]谭文渊.天然沸石的改性与表征及其去除生活废水中LAS的应用研究[D].成都:成都理工大学,2016.[7]刘嘉麒,张榆霞.滇池烷基苯磺酸钠的分布,降解及对鲤鱼的危害效应[J].重庆环境科学,1997,19(1):17-22.[8]YING G G,WILLIAMS B,KOOKANA R.Environmental fate of alkylphenols and alkylphenol ethoxylates：A review[J].Environment International,2003,28(3):215-226.[9]潘根兴,韩永镜,诸清河.太湖地区土壤环境中SAS的分布和降解特点[J].应用生态学报,2002(2):171-174.[10]CAI Q Y,HUANG H J,LU H X,et al.Occurrence of nonylphenol and nonylphenol monoethoxylate in soil and vegetables from vegetable farms in the Pearl River Delta,South China[J].Environ Contam Toxicol,2012,63(1):22-28.[11]谭志高,巢志茂,刘海萍,等.聚山梨脂80的化学稳定性研究进展[J].中国实验方剂学杂志,2012,18(1):251-254.[12]饶品华,肖稳发,徐菁利,等.表面活性剂对土壤持水特性的影响及其数学模拟[J].上海交通大学学报(农业科学版),2009,27(1):19-23.[13]ABDUL A S,GIBSON T L,RAI D N.Selection of surfactants for the removal of petroleum products from shallow sandy aquifers[J].Ground Water,1990,28(6):920-926.[14]蒋玲.表面活性剂对紫色土营养物质与重金属淋溶迁移的影响[D].重庆:西南大学,2009.[15]陈庆华.表面活性剂对土壤中氮磷迁移的影响[D].重庆:西南大学,2014.[16]SHANG Z X,ZHENG X L,MA Y F.Leaching treatment method of petroleum hydrocarbon pollution in farming land for ecological protection in China[J].Applied Ecology and Environmental Research,2019,17(4):9191-9204.[17]许中坚,陈津瑞.表面活性剂对土壤粘粒絮凝-分散的影响[J].环境科学研究,2003(3):62-64.[18]JAIN V,DEMOND A H.Conductivity reduction due to emulsification during surfactant enhanced-aquifer remediation.1.Emulsion transport[J].Environmental Science & Technology,2002,36(24):5426-5433.[19]董雯娟,赵保卫,蒋兵,等.阴-非混合表面活性剂对DNAPLs的增溶作用[J].安全与环境学报,2007(2):24-28.[20]陈刚,姜霞.复合表面活性剂(SDS/TW-80)对长链烷烃的增溶和柴油污染土壤的洗脱作用[J].农业环境科学学报,2010,29(7):1283-1289.
相似文献/References:
[1]李新荣,李顺江,杨金凤,等.密云水库上游河流入库段氮及磷的空间分布和评价[J].北方园艺,2014,38(08):152.
LI Xin-rong,LI Shun-jiang,YANG Jin-feng,et al.Spatial Distribution and Evaluation of Nitrogen and Phosphorus in Upstream Rivers in Miyun Reservoir[J].Northern Horticulture,2014,38(24):152.
[2]李寿田,钱剑林,韩建国,等.修剪条件下水分胁迫和磷处理对草地早熟禾草坪质量的影响[J].北方园艺,2013,37(18):56.
LI Shou-tian,QIAN Jian-lin,HAN Jian-guo,et al.Effects of Water Stress and Phosphorus Treatment on Turf Quality of Poa pratensis L.Under Mowing Conditions[J].Northern Horticulture,2013,37(24):56.
[3]周世玲,房岩,孙刚,等.菖蒲对污水中氮及磷的净化效应[J].北方园艺,2013,37(10):51.
ZHOU Shi-ling,FANG Yan,SUN Gang,et al.Effects of Acorus calamus on Nitrogen and Phosphorus Purification from Water[J].Northern Horticulture,2013,37(24):51.
[4]郑洁敏,牛天新,陈煜初,等.三十九种观赏挺水植物应用于人工浮岛水质净化潜力的比较[J].北方园艺,2013,37(06):72.
ZHENG Jie-min,NIU Tian-xin,CHEN Yu-chu,et al.Comparison of the Potential Water Purification by 39 Usually Used Ornamental Emerged Plants in the Artificial Floating Island[J].Northern Horticulture,2013,37(24):72.
[5]徐龙超,依艳丽,周晓阳.钙、磷平衡对番茄光合作用特性及防御酶活性的影响[J].北方园艺,2013,37(09):190.
XU Long-chao,YI Yan-li,ZHOU Xiao-yang.Effects of Calcium and Phosphorus Interaction on Photosynthesis and Defense Enzyme Activity of Tomato[J].Northern Horticulture,2013,37(24):190.
[6]杨涓,郑国琦,张磊.宁夏几种水生植物组合对氮磷吸收作用的研究[J].北方园艺,2012,36(16):56.
YANG Juan,ZENG Guo-qi,ZHANG Lei.Effects of Different Hydrophytes Combinations in Absorption of Nitrogen and Phosphorus in Ningxia[J].Northern Horticulture,2012,36(24):56.
[7]郝长红,颜 丽,胡克伟,等.沈阳福陵古松根区土壤养分状况研究[J].北方园艺,2012,36(18):185.
HAO Zhang-hong,YAN Li,HU Ke-wei,et al.Aged-pine’s Soil Nutrient Status Property of Root District in Shenyang Fu Imperial Tomb[J].Northern Horticulture,2012,36(24):185.
[8]刘旭富,石 青.五种水生植物对富营养化水体净化能力的研究[J].北方园艺,2012,36(22):54.
LIU Xu-fu,SHI Qing.Study on Purification Capacity of Five Kinds of Aquatic Plants on Eutrophic Water Body Purification Capacity[J].Northern Horticulture,2012,36(24):54.
[9]张占琴,战勇,张恒斌,等.氮、磷、钾对籽瓜产量和生理参数的影响[J].北方园艺,2012,36(21):166.
ZHANG Zhan-qin,ZHAN Yong,ZHANG Heng-bin,et al.Effects of Different Fertilizer Level of N，P，K on Physiological Parameters and Yield of Seed-Watermelon[J].Northern Horticulture,2012,36(24):166.
[10]杨晓玲,郭金耀.辣椒幼苗对富营养化养殖水的净化作用研究[J].北方园艺,2012,36(13):52.
YANG Xiao-ling,GUO Jin-yao.Effect of Water of Eutrophic Aquaculture on Pepper Seedling[J].Northern Horticulture,2012,36(24):52.
备注/Memo
第一作者简介：罗惠莉（1977-），女，博士，副教授，现主要从事环境监测与农业污染防控等研究工作。E-mail：luohuili@hunau.edu.cn.基金项目：第二次全国污染源普查专项资助项目（CLPSP18GZ02ZC95）；国家环境保护重金属污染监测重点实验室开放基金资助项目（SKLMHM202112）。收稿日期：2022-04-09